Here is the complete list of shortcuts:
Open Goldie Ruler
⌥ + ⌘ + G
Flip Horizontally
⌥ + ⇧ + ⌘ + H
Flip Horizontally
⌥ + ⇧ + ⌘ + V
Next Ruler Theme
⌥ + ⇧ + ⌘ + →
Previous Ruler Theme
⌥ + ⇧ + ⌘ + ←
Snap Rotate Ruler every 45°
Hold down shift as you rotate from the dot anchor point
Vertically and Horizontally Lock Ruler
Hold down shift as you drag from the middle white bar